The shipping in vTicket works on zones and this is the first part of the shipping you need to sort out – you enter rates against shipping types according to zones. A zone is defined as a group of countries and/or counties/states. For instance if you were running a site from the UK you might setup one zone that simply contains United Kingdom, another that contains all the European countries, one for America and another for the rest of the world.
With countries, once a country is marked to a zone it cannot be put in another zone unless it is first removed from the zone it is in or that zone is deleted. This stops you from putting a country in more than one zone which would give unpredictable results.
The main shipping zones page lists all the zones you have setup, by their name. Each one has an ‘Edit’ and ‘Delete’ button and in addition there is an ‘Add New Zone’ button at the bottom of the list to create a new zone.